Mann芳基醚脱烷基反应
芳基烷基醚（芳基烷基硫醚）和二芳基膦基锂（二芳基砷负离子）作用脱掉烷基的反应。
反应机理
反应实例
Phenol (4). An ice-cooled 2 (9.1 g, 50 mmol) in THF (110 mL) was treated with n-BuLi (1.24M, 45 mL). 1 (5.8 g, 53 mmol) was added and the red solution was refluxed for 4 h. Evaporation, addition of Et2O, water and distillation afforded 8.5 g of 5 (87%), bp 87–90 C/0.2 mmfrom Et2O, and 3.81 g of 4 (83%) from the aq layer.
【Mann FG, J Chem Soc, 1965, 4120】
相关文献
1 Mann FG J Chem Soc 1963 1155
2 Mann FG Chem Ind 1963 1558
3 Mann FG Chem Ind 1964 1386
4 Mann FG J Chem Soc 1965 4120
5 Veriott G Acros Org Acta 1995 1 40
6 Furukawa N Chem Comm 2000 1667
7 Weissman SA Tetrahedron 2005 61 7833
8 Nishida A Eur J Org Chem 2006 752
编译自：Organic Syntheses Based On Name Reactions, 3RdEd, A. Hassner, Page 301.
相关反应
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