河南大学王新海组和华东理工大学吕树光组--可回收聚多巴胺官能化RGO/铁纳米复合材料用于增强1,1,1-三氯乙烷的降解
通过非均相催化剂从地下水中去除氯代烃已成为一种有价值的方法。但是，合成高效且持久的材料，尤其是用于去除三氯乙烷（TCA）的方法仍不成熟。在这项研究中，我们通过pH诱导的多巴胺聚合反应制备了聚多巴胺（PDA）嵌入的Fe/rGO纳米复合材料，用于在过碳酸钠（SPC）体系中降解TCA。实验结果表明，与裸露的Fe/rGO相比，PDA装饰的Fe/rGO不仅更经济地提高了TCA降解（98％），而且还增强了催化剂的稳定性和可回收性。TEM、XRD、FTIR、XPS和VSM分析表明成功制备了磁性可分离的PDA@Fe/rGO纳米复合材料。此外，PDA@Fe/rGO/SPC系统中探针化合物的较高降解速率表明，由于多巴胺的自氧化作用，PDA的装饰改善了活性物质的形成，并降低了PDA的能力。溶液基质对PDA@Fe/rGO性能的影响阐明了各种物质对降解的影响。GCMS、TOC分析和脱氯实验验证了无毒产品的形成以及合理的TOC和氯离子去除效果。PDA@Fe/rGO催化剂可循环使用六个连续周期，保持76％的利用率，并通过XRD和XPS分析验证了Fe2+和Fe3+物种的丰富可用性。PDA@Fe/rGO纳米复合材料增强的修复能力和改进的可回收性可为地下水中三氯乙酸的实际应用提供闪耀的新星。
Figure 1. 合成纳米复合材料的表面形态，a）Fe/rGO和b）PDA@Fe/rGO的SEM分析，c）Fe/rGO和d）PDA@Fe/rGO的TEM分析（插图HRTEM）
Figure 2. PDA@Fe/rGO的HAADF-EDS映射。
Figure 3. 溶液基质对TCA降解的影响：a）HCO3-和b）Cl-（[PDA@Fe/rGO]=0.4 g/L，[SPC]=15 mM，[TCA]o=0.15 mM）。
Figure 4. 在不同的无机离子下：a）NO3-和b）SO42-（[PDA@Fe/rGO]=0.4g/L，[SPC]=15 mM，[TCA]o=0.15 mM），TCA的降解性能。
Figure 5. 在[PDA@Fe/rGO]=0.4g/L，[TCA]o=0.15 mM，各种剂量SPC的存在下，TOC的去除。
相关研究成果于2021年由河南大学Xinhai Wang课题组和华东理工大学Shuguang Lyu课题组，发表在Chemical Engineering Journal（https://doi.org/10.1016/j.cej.2020.126405）上。原文：A recyclable polydopamine-functionalized reduced graphene oxide/Fe nanocomposite (PDA@Fe/rGO) for the enhanced degradation of 1,1,1-trichloroethane。
王新海，日本国立山口大学环境工程博士，河南大学副教授，硕士生导师，九三学社开封市市委委员。日本水环境学会（JSWE）会员，中国化学会（CCS）会员，河南省化学会理事，河南省工业冷却水循环利用工程技术研究中心副主任，河南省水资源循环与治理产业技术创新战略联盟总工程师。河南省爱可沃德生态科技有限公司董事长。
教育与工作经历
1994.09 – 1998.06 河南大学化学化工学院高分子化工专业，工学学士
1998.07 – 2001.05 开封师范高等专科学校化学系助教
2001.05 – 2005.03 河南大学化学化工学院助教、讲师
2005.04 – 2005.10 JBIC中国内陆地区人才项目，日本国立山口大学研究者
2005.10 – 2009.03 日本国立山口大学大学院环境共生工学，工学博士
2008.10 - 2009.10 日本国立山口大学产学连携研究中心外国人研究者
2009.04 - 河南大学，环境与分析科学研究所，讲师、副教授
2012.09 - 2013.09 开封市龙宇化工有限公司，副总经理
研究方向：1.水处理新技术、新装备开发与应用；2.厌氧消化中硫酸盐还原菌的活性抑制；3.环境功能材料
主讲课程：《环境监测》、《环保设备基础》、《环境科学与工程专题研究与前沿》
主持项目：
1. 五效立体富营养化集成处理系统（FEST）关键技术研发及产业化. 河南省重大科技专项(CX0001F01800), 500万元，2016.06-2018.06, 主持。
2. 基于双膜理论的固液分离技术及应用. 横向项目(2222F08665), 160万元. 2012.09-2014.09 主持。
3. 气浮工艺中新型固液分离技术的应用. 横向课题, 144万元, 2014.09.26-2015.09.26 主持。
4. 基于双膜理论的固液分离技术及应用. 2013年度河南省产学研合作项目（132107000004）, 以奖代补68万元, 2012.9-2014.9 主持。
5. 中泉集团环境测试中心建设项目. 企业内部创新项目, 合同额200万元, 2010.10-2011.09 主持。
6. 中泉集团PAN超滤膜组件生产线辅助项目. 企业内部创新项目，合同额60万元，2010.10-2012. 主持。
7. 含硫酸盐废水厌氧处理过程中SRB对MPB的毒性控制. 河南省教育厅科学技术研究重点项目(13A610047), 5万元. 2013.01-2015.12 主持。
8. 厌氧消化过程中的沼气促产机制研究. 教育部留学回国人员科研启动基金(2013.210), 3万元. 2013.02-2016.02 主持。
9. FEST集成处理系统的工程化应用. 河南大学2016年度省校区合作奖励补助资金, (CX50000A65007), 12万元, 2016.01-2017.01 主持。
10. 全太阳能无人驾驶水生态保障船. 上海市高端智能装备首台突破和示范应用专项. 251万元，2017.06-2019.06 主持。
主要奖励：
1.2017年中国产学研合作创新奖（证书号：20173097），国科奖社证字第0191号，2017.11，中国产学研合作促进会，主持。
2.太阳能自动驾驶水生态保障船，第十九届中国国际工业博览会高校展区优秀展品奖二等奖，2017.11，中国国际工业博览会高校展区组委会，主持。
3. 第九届全国大学生节能减排社会实践与科技竞赛，三等奖，指导教师。
另：授权发明专利6项，实用新型专利18项，发表学术论文10篇。
吕树光学历及工作经历：
1986年 毕业于天津大学，获环境工程专业学士学位
1989年 毕业于天津大学，获环境工程专业工学硕士学位
1989.4–1996.11 沈阳市规划设计研究院，工程师
1996.11–1997.3 日本山口大学工学部，访问学者
2000年 毕业于日本山口大学环境与生态工学专业，获工学博士学位
2000.4–2002.11 日本山口大学，日本学術振兴会外国人特别研究员
2002.11–2005.9 英国北方高地学院环境研究所，主要项目负责人及博士生导师
2005.10– 华东理工大学资源与环境工程学院，教授及博士生导师
学术兼职：
任《环境污染与防治》编委；“Frontiers of Environmental Science & Engineering”编委；任 International Water Association (IWA) 会员。
近几年来的主要研究方向：
（ 1 ）污染场地修复治理；
（ 2 ）生活及工业废水处理技术；
（ 3 ）药物在水环境中的行为机制及其对生态环境的影响；
（ 4 ）活性污泥法数学模型与计算机仿真技术的研究。
科研项目：
2020年，主持国家自然科学基金面上项目：FeS催化缓释纳米CaO2一体化类Fenton高级氧化材料的创制及其降解氯代烃的作用机制。
2019年，主持地矿工程勘察院合作项目：二次污染物的生成特征单元体试验研究。
2018年，主持国家重点研发计划：卤代溶剂异位分离与净化技术装备。
2018年，主持上海市科委国际合作交流项目：FeS强化一体化纳米类Fenton高级氧化技术对氯代烃污染地下水治理效果及机制的研究。
2018年，参与国家重点研发计划：石化场地绿色低耗原位修复技术装备开发。
2018年，主持地矿工程勘察院合作项目：河道底泥重金属固定稳定化及淋洗去除技术研究。
2018年，主持浙江省环境工程有限公司合作项目：西湖区黑臭河道治理后富营养化分析研究。
2018年，主持中国水利水电第十二局有限公司合作项目：基于高级氧化技术的河流底泥污染长效生态治理技术研究。
2014年，主持国家自然科学基金面上项目：过硫酸盐活化体系中共存在的氧化/还原自由基对地下水氯代烃的降解贡献度及机制研究。
2013年，参与国家自然科学基金青年基金：污水厂二级出水水质对臭氧深度处理去除药物和个人护理品的影响及机理研究。
2013年，主持宝山钢铁股份有限公司合作项目：焦化废水浓水处理工艺试验研究。
2013年，主持海宝钢化工有限公司合作项目：焦化废水除氰工艺优化研究。
2012年，主持液化空气（中国）投资有限公司合作项目：空气与氧气活性污泥工艺处理中国典型造纸废水的工艺对比研究。
2011年，主持国家环境保护公益性行业科研专项：我国地下水氯代烃污染现状与监管技术研究。
2008年，参与863项目子课题：高风险有机污染物污染地下水联合修复技术研究。
2007年，主持上海市轻工业研究所合作项目：全自动扩散渗析工业废酸回收设备技术开发。
2007年，主持上海市浦江人才计划：包含溶解性微生物产物形成与降解机理的活性污泥数学模型建立及参数确定。
2007年，主持宝山钢铁股份有限公司合作基金项目：冷轧平整废液预处理工艺研究。
2004年，主持Macallan Distillery威士忌酒厂废水中金属铜去处技术的开发（European Research and Development Funding）。
2003年，主持Highland Council，AMEC Co. Ltd及University of Liverpool联合项目：Caithness地区有机固体废弃物的厌氧消化及能源回收可行性研究。
2000年，主持有机固体废弃物的好氧与厌氧堆肥效果的评价（日本文部省项目）。
1998年，主持日本协和发酵工厂高浓度废水处理：膜生物反应器处理技术的研究。
1987年，参与天津市纪庄子污水处理厂二级出水回用：臭氧预处理连续流微絮凝过滤的研究，获国家环境保护局“七.五”攻关课题重大成果奖。
教学：
0822028701 本科生 科技英语（32学时）
J481-051 博士研究生 污染场地修复治理技术（16学时）
论著：
1. 现代工程科学与技术丛书：环境科学与工程，科学出版社，2007.8，ISBN 978-7-03-019756-6，参编
2. Chemical Engineering in Sustainable Development, Edited by Xuhong Qian and Jingping Qu, 2008, July, Dalian University of Technology Press, ISBN: 978-7-5611-4285-1，参编
主要论文：
1. Wenchao Jiang, Dionysios D. Dionysioub*, Minghao Kong, Zhen Liu, Qian Sui, Shuguang Lyu*. Utilization of formic acid in nanoscale zero valent iron-catalyzed Fenton system for carbon tetrachloride degradation. Chemical Engineering Journal, 2020, 380: 122537.
2. Wenchao Jiang, Ping Tang, Shuguang Lyu*, Mark L. Brusseau, Yunfei Xue, Xiang Zhang, Zhaofu Qiu, Qian Sui*. Enhanced redox degradation of chlorinated hydrocarbons by the Fe(II)-catalyzed calcium peroxide system in the presence of formic acid and citric acid. Journal of Hazardous Materials, 2019, 368: 506-513.
3. Ping Tang, Wenchao Jiang, Shuguang Lyu*, Mark L. Brusseau, Yunfei Xue, Zhaofu Qiu, Qian Sui*. Mechanism of carbon tetrachloride reduction in ferrous ion activated calcium peroxide system in the presence of methanol. Chemical Engineering Journal, 2019, 362: 243-250.
4. Yunfei Xue, Qian Sui*, Mark L. Brusseau, Wei Zhou, Zhaofu Qiu, Shuguang Lyu*. Insight into CaO2-based Fenton and Fenton-like systems: strategy for CaO2-based oxidation of organic contaminants. Chemical Engineering Journal, 2019, 361: 919-928.
5. Yong Sun, Shuguang Lyu*, Mark L. Brusseau, Ping Tang, Wenchao Jiang, Mengbin Gu, Ming Li, Yanchen Lyu, Zhaofu Qiu, Qian Sui*. Degradation of trichloroethylene in aqueous solution by nanoscale calcium peroxide in the Fe(II)-based catalytic environments, Separation and Purification Technology. 2019, 226: 13-21.
6. Usman Farooq, Muhammad Danish, Shuguang Lyu*, Mark L. Brusseau, Mengbin Gu, Waqas Qamar Zaman, Zhaofu Qiu, Qian Sui. The impact of surface properties and dominant ions on the effectiveness of G-nZVI heterogeneous catalyst for environmental remediation. Science of the Total Environment, 2019, 651: 1182-1188.
7. Mengbin Gu, Qian Sui, Usman Farooq, Xiang Zhang, Zhaofu Qiu, Shuguang Lyu*. Degradation of phenanthrene in sulfate radical based oxidative environment by nZVI-PDA functionalized rGO catalyst. Chemical Engineering Journal, 2018, 354: 541-552.
8. Yunfei Xue, Qian Sui, Mark L. Brusseau, Xiang Zhang, Zhaofu Qiu, Shuguang Lyu*. Insight on the generation of reactive oxygen species in the CaO2/Fe(II) Fenton system and the hydroxyl radical advancing strategy. Chemical Engineering Journal, 2018, 353: 657-655.
9. Mengbin Gu, Qian Sui, Usman Farooq, Xiang Zhang, Zhaofu Qiu, Shuguang Lyu*. Enhanced degradation of trichloroethylene in oxidative environment by nZVI/PDA functionalized rGO catalyst. Journal of Hazardous Materials, 2018, 359: 157-165.
10. Yunfei Xue, Ljiljana Rajic, Long Chen, Shuguang Lyu*, Akram N. Alshawabkeh. Electrolytic control of hydrogen peroxide release from calcium peroxide in aqueous solution. Electrochemistry Communications, 2018, 93: 81-85.
11. Ping Tang, Wenchao Jiang, Shuguang Lyu*, Zhaofu Qiu, Qian Sui. Ethanol enhanced carbon tetrachloride degradation in Fe (II) activated calcium peroxide system. Separation and Purification Technology, 2018, 205: 105-112.
12. Usman Farooq, Muhammad Danish, Shuguang Lu*, Muhammmad Naqvi, Zhaofu Qiu, Qian Sui. A step forward towards synthesizing a stable and regeneratable nanocomposite for remediation of trichloroethene. Chemical Engineering Journal, 2018, 347: 660-668.
13. Wenchao Jiang, Ping Tang, Shuguang Lu*, Yunfei Xue, Xiang Zhang, Zhaofu Qiu, Qian Sui. Comparative studies of H2O2/Fe(II)/formic acid, sodium percarbonate/Fe(II)/formic acid and calcium peroxide/Fe(II)/formic acid processes for degradation performance of carbon tetrachloride. Chemical Engineering Journal, 2018, 344: 453-461.
14. Mengbin Gu, Usman Farooq, Shuguang Lu*, Xiang Zhang, Zhaofu Qiu, Qian Sui. Degradation of trichloroethylene in aqueous solution by rGO supported nZVI catalyst under several oxic environments. Journal of Hazardous Materials, 2018, 349: 35-44.
15. Sixia Yu, Xiaogang Gu, Shuguang Lu*, Yunfei Xue, Xiang Zhang, Minhui Xu, Zhaofu Qiu, Qian Sui. Degradation of phenanthrene in aqueous solution by a persulfate/percarbonate system activated with CA chelated-Fe(II). Chemical Engineering Journal, 2018, 333: 122-131.
16. Yunfei Xue, Shuguang Lu*, Xiaori Fu, Virender K.Sharma, Itza Mendoza-Sanchez, Zhaofu Qiu, Qian Sui. Simultaneous removal of benzene, toluene, ethylbenzene and xylene (BTEX) by CaO2 based Fenton system: Enhanced degradation by chelating agents. Chemical Engineering Journal, 2018, 331: 255-264.
17. Xiaogang Gu, Shuguang Lu*, Xiaori Fu, Zhaofu Qiu, Qian Sui, Xuhong Guo. Carbon dioxide radical anion-based UV/S2O82-/HCOOH reductive process for carbon tetrachloride degradation in aqueous solution. Separation and Purification Technology, 2017, 172: 211-216.
18. Muhammad Danish, Xiaogang Gu, Shuguang Lu*, Ayyaz Ahmad, Muhammad Naqvi, Usman Farooq, Xiang Zhang, Xiaori Fu, Zhouwei Miao, Yunfei Xue. Efficient transformation of trichloroethylene activated through sodium percarbonate using heterogeneous zeolite supported nano zero valent iron-copper bimetallic composite. Chemical Engineering Journal, 2017, 308: 396-407.
19. Hang Cui, Xiaogang Gu, Shuguang Lu*, Xiaori Fu, Xiang Zhang, George Y. Fu, Zhaofu Qiu, QianSui. Degradation of ethylbenzene in aqueous solution by sodium percarbonate activated with EDDS-Fe(III) complex. Chemical Engineering Journal, 2017, 309: 80-88.
20. Muhammad Danish, Xiaogang Gu, Shuguang Lu*, Mark L. Brusseau, Ayyaz Ahmad, Muhammad Naqvi, Usman Farooq, Waqas Qamar Zaman, Xiaori Fu, Zhouwei Miao. An efficient catalytic degradation of trichloroethene in a percarbonate system catalyzed by ultra-fine heterogeneous zeolite supported zero valent iron-nickel bimetallic composite. Applied Catalysis A: General, 2017, 531: 177-186.
21. Usman Farooq, Muhammad Danish, Shuguang Lu*, Mark L. Brusseau, Muhammmad Naqvi, Xiaro Fu, Xiang Zhang, Qian Sui, Zhaofu Qiu. Efficient transformation in characteristics of cations supported-reduced graphene oxide nanocomposites for the destruction of trichloroethane. Applied Catalysis A: General, 2017, 544: 10-20.
22. Shuguang Lu*, Xiang Zhang, Yunfei Xue. Application of calcium peroxide in water and soil treatment: A review. Journal of Hazardous Materials, 2017, 337: 163-177.
23. Xiang Zhang, Xiaogang Gu, Shuguang Lu*, Mar L. Brusseau, Minhui Xu, Xiaori Fu, Zhaofu Qiu, Qian Sui. Application of ascorbic acid to enhance trichioroethene degradation by Fe(III)-activated calcium peroxide. Chemical Engineering Journal, 2017, 325: 188-198.
24. Xiang Zhang, Xiaogang Gu, Shuguang Lu*, Zhouwei Miao, Minhui Xu, Xiaori Fu, Zhaofu Qiu, Qian Sui. Application of calcium peroxide activated with Fe(II)-EDDS complex in trichloroethylene degradation. Chemosphere, 2016, 160: 1-6.
25. Xiaori Fu, Xiaogang Gu, Shuguang Lu*, Minhui Xu, Zhouwei Miao, Xiang Zhang, Yacong Zhang, Yunfei Xue, Zhaofu Qiu, Qian Sui. Enhanced degradation of benzene in aqueous solution by sodium percarbonate activated with chelated-Fe(II). Chemical Engineering Journal, 2016, 285: 180-188.
26. Yunfei Xue, Xiaogang Gu, Shuguang Lu*, Zhouwei Miao, Mark L. Brusseau, Minhui Xu, Xiaori Fu, Xiang Zhang, Zhaofu Qiu, Qian Sui. The destruction of benzene by calcium peroxide activated with Fe(II) in water. Chemical Engineering Journal, 2016, 302: 187-193.
27. Zhouwei Miao, Xiaogang Gu, Shuguang Lu*, Mark L. Brusseau, Ni Yan, Zhaofu Qiu, Qian Sui. Enhancement effects of reducing agents on the degradation of tetrachloroethene in the Fe(II)/Fe(III) catalyzed percarbonate system. Journal of Hazardous Materials, 2015, 300: 530-537.
28. Xiaoliang Wu, Xiaogang Gu, Shuguang Lu*, Zhaofu Qiu, Qian Sui, Xueke Zang, Zhouwei Miao, Minhui Xu. Strong enhancement of trichloroethylene degradation in ferrous ion activated persulfate system by promoting ferric and ferrous ion cycles with hydroxylamine. Separation and Purification Technology, 2015, 147: 186-193.
29 Xiaori Fu, Xiaogang Gu, Shuguang Lu*, Zhouwei Miao, Minhui Xu, Xiang Zhang, Zhaofu Qiu, Qian Sui. Benzene depletion by Fe2+-catalyzed sodium percarbonate in aqueous solution. Chemical Engineering Journal, 2015, 267: 25-33.
30. Minhui Xu, Xiaogang Gu, Shuguang Lu*, Zhaofu Qiu, Qian Sui, Zhouwei Miao, Xueke Zang, Xiaoliang Wu. Degradation of carbon tetrachloride in aqueous solution in the thermally activated persulfate system. Journal of Hazardous Materials, 2015, 286: 7-14.
31. Xiang Zhang, Xiaogang Gu, Shuguang Lu*, Zhouwei Miao, Minhui Xu, Xiaori Fu, Zhaofu Qiu, Qian Sui. Degradation of trichloroethylene in aqueous solution by calcium peroxide activated with ferrous ion. Journal of Hazardous Materials, 2015, 284: 253-260.
32. Zhouwei Miao, Xiaogang Gu, Shuguang Lu*, Mark L. Brusseau, Xiang Zhang, Xiaori Fu, Muhammad Danish, Zhaofu Qiu, Qian Sui. Enhancement effects of chelating agents on the degradation of tetrachloroethene in Fe(III) catalyzed percarbonate system. Chemical Engineering Journal, 2015, 281: 286-294.
33. Landry Biyoghe Bi Ndong, Xiaogang Gu, Shuguang Lu*, Murielle Primaelle Ibondou, Zhaofu Qiu, Qian Sui, Serge Maurice Mbadinga, Bozhong Mu. Role of reactive oxygen species in the dechlorination of trichloroethene and 1,1,1-trichloroethane in aqueous phase in UV/TiO2 systems. Chemical Engineering Science, 2015, 123: 367-375.
34. Zhouwei Miao, Xiaogang Gu, Shuguang Lu*, Dionysios D. Dionysiou, Souhail R. Al-Abed, Xueke Zang, Xiaoliang Wu, Zhaofu Qiu, Qian Sui, Muhammad Danish. Mechanism of PCE oxidation by percarbonate in a chelated Fe(II)-based catalyzed system. Chemical Engineering Journal, 2015, 275: 53-62.
35. Zhouwei Miao, Xiaogang Gu, Shuguang Lu*, Xuke Zang, Xiaoliang Wu, Minhui Xu, Landry Biyoghe Bi Ndong, Zhaofu Qiu, Qian Sui, George Yuzhu Fu. Perchloroethylene (PCE) oxidation by percarbonate in Fe2+-catalyzed aqueous solution: PCE performance and its removal mechanism. Chemosphere, 2015, 119: 1120-1125.
36. Xiaoliang Wu, Xiaogang Gu, Shuguang Lu*, Minhui Xu, Xueke Zang, Zhouwei Miao, Zhaofu Qiu, Qian Sui. Degradation of trichloroethylene in aqueous solution by persulfate activated with citric acid chelated ferrous ion. Chemical Engineering Journal, 2014, 255: 585-592.
37. Xiaogang Gu, Shuguang Lu*, Zhaofu Qiu, Qian Sui, Charles J. Banks, Tsuyoshi Imai, Kuangfei Lin, Qishi Luo. Photodegradation performance of 1,1,1-trichloroethane in aqueous solution: in the presence and absence of persulfate. Chemical Engineering Journal, 2013, 215: 29-35.
38. Ji Fan, Peter A. Vanrolleghem, Shuguang Lu*. A kinetic modeling for carbon metabolism in sequencing batch reactor under multiple aerobic/anoxic conditions. Applied Microbiology and Biotechnology, 2012, 96: 241-252.
39. Qian Sui, Bin Wang, Wentao Zhao, Jun Huang, Gang Yu, Shubo Deng, Zhaofu Qiu, Shuguang Lu*. Identification of priority pharmaceuticals in the water environment of China. Chemosphere, 2012, 89: 280-286.
40. Ji Fan, Peter A. Vanrolleghem, Zhaofu Qiu, Shuguang Lu*. Modification of the kinetics for modeling substrate storage and biomass growth mechanism in activated sludge system under aerobic condition. Chemical Engineering Science, 2012, 78: 75-81.
41. Xiaogang Gu, Shuguang Lu*, Zhaofu Qiu, Qian Sui, Zhouwei Miao, Kuangfei Lin, Yongdi Liu, Qishi Luo. Comparison of photodegradation performance of 1,1,1-trichloroethane in aqueous solution with the addition of H2O2 or S2O82− oxidants. Industrial & Engineering Chemistry Research, 2012, 51: 7196-7204.
42. Xiaogang Gu, Shuguang Lu*, Lin Li, Zhaofu Qiu, Qian Sui, Kuangfei Lin, Qishi Luo. Oxidation of 1,1,1-trichloroethane stimulated by thermally activated persulfate. Industrial & Engineering Chemistry Research, 2011, 50: 11029-11036.
43. Wenzhen Li, Shuguang Lu*, Zhaofu Qiu, Kuangfei Lin. Photocatalysis of clofibric acid under solar light in summer and winter seasons. Industrial & Engineering Chemistry Research, 2011, 50: 5384-5393.
44. Wenzhen Li, Shuguang Lu*, Zhaofu Qiu, Kuangfei Lin. Clofibric acid degradation in UV254/H2O2 process: effect of temperature. Journal of Hazardous Materials, 2010, 176: 1051–1057.
45. Xiaoxia Wang, Zhaofu Qiu, Shuguang Lu*, Weiqi Ying. Characteristics of organic, nitrogen and phosphorus species released from ultrasonic treatment of waste activated sludge. Journal of Hazardous Materials, 2010, 176: 35-40.
46. Jing Xu, Dan Fu, Shuguang Lu*. The recovery of sulphuric acid from the waste anodic aluminum oxidation solution by diffusion dialysis. Separation and Purification Technology, 2009, 69: 168–173.
47. Jing Xu, Shuguang Lu*, Dan Fu. Recovery of hydrochloric acid from the waste acid solution by diffusion dialysis. Journal of Hazardous Materials, 2009, 165: 832-837.
48. Shuguang Lu*, Stuart W. Gibb. Copper removal from wastewater using spent-grain as biosorbent. Bioresource Technology, 2008, 99: 1509-1517.
49. Shuguang Lu*，Stuart W. Gibb, Emma Cochrane. Effective removal of zinc ions from aqueous solutions using crab carapace biosorbent. Journal of Hazardous Materials, 2007, 149: 208-217.
50. Shuguang Lu, T. Imai*, M. Ukita, M. Sekine, M. Fukagawa, H. Nakanishi. A model for membrane bioreactor process based on the concept of formation and degradation of soluble microbial products. Water Research, 2001, 35: 2038-2048.