Elbs氧化

此反应也被称为 Elbs过硫酸盐氧化,此反应与Boyland–Sims类似只是底物由苯胺变为苯酚,机理也与其类似。

反应机理

对位反应位点的特点是由于苯酚的互变异构体决定的,过硫酸盐的氧原子对苯酚进行亲电取代,水解得到产物。

参考文献

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编译自:J.J. Li, Name Reactions: A Collection of Detailed Mechanisms and Synthetic Applications, Elbs oxidationpage 76.

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