Dötz反应

此反应也被称为 Dötz 苯环化反应，烯基烷氧基五羰基合铬卡宾络合物（Fischer 卡宾）和炔反应生成Cr(CO)3络合的对苯二酚的反应。

反应机理

反应实例

参考文献

1. Dötz, K. H. Angew. Chem. Int. Ed. 1975, 14, 644􀀐-645. Karl H. Dötz (1943􀀐) was a professor at the University of Munich in Germany.

2. Wulff, W. D. In Advances in Metal-Organic Chemistry; Liebeskind, L. S., Ed.; JAI Press, Greenwich, CT; 1989; Vol. 1. (Review).

3. Wulff, W. D. In Comprehensive Organometallic Chemistry II; Abel, E. W., Stone, F. G. A., Wilkinson, G., Eds.; Pergamon Press: Oxford, 1995; Vol. 12. (Review).

4. Torrent, M.; Solá, M.; Frenking, G. Chem. Rev. 2000, 100, 439􀀐-494. (Review).

5. Caldwell, J. J.; Colman, R.; Kerr, W. J.; Magennis, E. J. Synlett 2001, 1428-􀀐1430.

6. Solá, M.; Duran, M.; Torrent, M. The Dötz reaction: A chromium Fischer carbenemediated benzannulation reaction. In Computational Modeling of Homogeneous Catalysis Maseras, F.; Lledós, eds.; Kluwer Academic: Boston; 2002, 269􀀐-287. (Review).

7. Pulley, S. R.; Czakó, B. Tetrahedron Lett. 2004, 45, 5511􀀐-5514.

8. White, J. D.; Smits, H. Org. Lett. 2005, 7, 235-􀀐238.

9. Boyd, E.; Jones, R. V. H.; Quayle, P.; Waring, A. J. Tetrahedron Lett. 2005, 47,

7983-􀀐7986.

10. Fernandes, R. A.; Mulay, S. V. J. Org. Chem. 2010, 75, 7029–7032.

编译自：Name Reactions （A Collection of Detailed Reaction Mechanisms）, Jie Jack Li, Dötz reaction，page 223-224.